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Iron isotope compositions in marine pore fluids and sedimentary solid phases were measured at two sites along the California continental margin, where isotope compositions range from δ56Fe = −3.0‰ to +0.4‰. At one site near Monterey Canyon off central California, organic matter oxidation likely proceeds through a number of diagenetic pathways that include significant dissimilatory iron reduction (DIR) and bacterial sulfate reduction, whereas at our other site in the Santa Barbara basin DIR appears to be comparatively small, and production of sulfides (FeS and pyrite) was extensive. The largest range in Fe isotope compositions is observed for Fe(II)aq in porewaters, which generally have the lowest δ56Fe values (minimum: −3.0‰) near the sediment surface, and increase with burial depth. δ56Fe values for FeS inferred from HCl extractions vary between ∼−0.4‰ and +0.4‰, but pyrite is similar at both stations, where an average δ56Fe value of −0.8 ± 0.2‰ was measured. We interpret variations in dissolved Fe isotope compositions to be best explained by open-system behavior that involves extensive recycling of Feflux. This study is the first to examine Fe isotope variations in modern marine sediments, and the results show that Fe isotopes in the various reactive Fe pools undergo isotopic fractionation during early diagenesis. Importantly, processes dominated by sulfide formation produce high-δ56Fe values for porewaters, whereas the opposite occurs when Fe(III)-oxides are present and DIR is a major pathway of organic carbon respiration. Because shelf pore fluids may carry a negative δ56Fe signature it is possible that the Fe isotope composition of ocean water reflects a significant contribution of shelf-derived iron to the open ocean. Such a signature would be an important means for tracing iron sources to the ocean and water mass circulation.  相似文献   
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The Rhodope Metamorphic Province represents the core of an Alpine orogen affected by strong syn- and postorogenic extension. We report evidence for multiple phases of extensional unroofing from the western border of the Rila Mountains in the lower Rila valley, SW Bulgaria. The most prominent structure is the Rila-Pastra Normal Fault (RPNF), a major extensional fault and shear zone of Eocene to Early Oligocene age. The fault zone includes, from base to top, mylonites, ultramylonites and cataclasites, indicating deformation under progressively decreasing temperature, from amphibolite-facies to low-temperature brittle deformation. It strikes E–W with a top-to-the-N-to NW-directed sense of shear. Basement rocks in the hanging wall and footwall both display amphibolite-facies conditions. The foliation of the hanging-wall gneisses, however, is discordantly cut by the fault, while the foliation of the footwall gneisses is seen to curve into parallelism with the fault when approaching it. Two ductile splays of the RPNF occur in the footwall, which are subparallel to the foliation of the surrounding gneisses and merge laterally into the mylonites of the main fault zone. The concordance between the foliation in the footwall and the RPNF suggests that deformation and cooling in the footwall occurred simultaneously with extensional shearing, while the hanging-wall gneisses had already been exhumed previously. The RPNF is associated with thick deposits of an Early Oligocene, syntectonic breccia on top of its hanging wall. Integrating our results with previous studies, we distinguish the following stages of extensional faulting: (1) Late Cretaceous NW–SE extension (Gabrov Dol Detachment), exhumation of the present day hanging wall of the RPNF; (2) Eocene to Early Oligocene NW–SE to N–S extension (RPNF); (3) Miocene to Pliocene E–W extension (Western Border Fault), formation of the Djerman Graben; (4) Holocene to recent N–S to NW–SE extension (Stob Fault), reactivating the SW part of the Western Border Fault.  相似文献   
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The structure of atmospheric turbulence in the surface layer over the open ocean is examined under conditions of local free convection. The raw data consist of profile and fluctuation measurements of wind and temperature as obtained from a meteorological buoy. For near neutral conditions and for waves running approximately along the wind direction, wave-induced wind fluctuations can be described by a simplified linear theory based on Miles (1957). In this case, the spectrum of wind velocity is given as the sum of two parts; for the turbulent part, the parameterization as obtained by Kaimal et al. (1972) applies, while the wave-induced part is parameterized using a simplification of Miles' linear theory. For cases of local free convection, the measurements of the vertical component of the wind velocity are well described by similarity theory; as expected, w /(-uw)1/2 is proportional to (- z/L)1/3. In order to scale the longitudinal wind velocity component, it seems to be reasonable to extend the list of relevant parameters by the height of the mixed layer z i. We obtain u /(- uw)1/2 (z/z i)1/3(- z/L)1/3 with only a poor correlation coefficient of r = 0.6. Overall, the results of local free convection scaling obtained from direct measurements show good agreement with those obtained from profile measurements. A comparison between direct and indirect determination of turbulent fluxes of momentum shows an unexplained difference of about 20%. This discrepancy is mainly due to a gap in the uw-cospectrum at the swell frequency.  相似文献   
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Advances in the chemical, crystallographic and isotopic characterisation of geological and environmental materials can often be ascribed to technological improvements in analytical hardware or to innovative approaches to data acquisition and/or its interpretation. This biennial review addresses key laboratory methods that form much of the foundation for analytical geochemistry; again, this contribution is presented as a compendium of laboratory techniques. We highlight advances that have appeared since January 2012 and that are of particular significance for the chemical and isotopic characterisation of geomaterials. Prominent scientists from the selected analytical fields present publications they judge to be particular noteworthy, providing background information about the method and assessing where further opportunities might be anticipated. In addition to the well‐established technologies such as thermal ionisation mass spectrometry and plasma emission spectroscopy, this publication also presents new or rapidly growing methods such as electron backscattered diffraction analysis and atom probe tomography – a very sensitive method providing atomic scale information.  相似文献   
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